Radical 1,2-aryl migration in α,α-diaryl allylic alcohols toward β-silyl ketones.

نویسندگان

  • Haibo Peng
  • Jin-Tao Yu
  • Yan Jiang
  • Jiang Cheng
چکیده

A copper-catalyzed radical 1,2-aryl migration in α,α-diaryl allylic alcohols is developed, leading to β-silyl carbonyl compounds in moderate to good yields. The migration of aryls with lower aromaticity is favored. This procedure features the employment of silanes as commercially available materials.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 13 41  شماره 

صفحات  -

تاریخ انتشار 2015